Organic certification for Alcoholic

Courtesy: Organic certification for Alcoholic

Isopropyl alcohol (IUPAC name propan-2-ol and also called isopropanol or 2-propanol) is a colorless, flammable organic compound (chemical formula CH₃CHOHCH₃) with a strong alcoholic odor. As an isopropyl group linked to a hydroxyl group, it is the simplest example of a secondary alcohol, where the alcohol carbon atom is attached to two other carbon atoms. It is a structural isomer of propan-1-ol and ethyl methyl ether.

It is used in the manufacture of a wide variety of industrial and household chemicals and is a common ingredient in products such as antiseptics, disinfectants, hand sanitizer and detergents. Well over one million tonnes is produced worldwide annually.

Isopropyl alcohol is miscible in water, ethanol, and chloroform as, like these compounds, isopropyl is a polar molecule. It dissolves ethyl cellulose, polyvinyl butyral, many oils, alkaloids, and natural resins. Unlike ethanol or methanol, isopropyl alcohol is not miscible with salt solutions and can be separated from aqueous solutions by adding a salt such as sodium chloride. The process is colloquially called salting out, and causes concentrated isopropyl alcohol to separate into a distinct layer.

Isopropyl alcohol forms an azeotrope with water, which gives a boiling point of 80.37 °C (176.67 °F) and a composition of 87.7% by mass (91% by volume) isopropyl alcohol. Alcohol mixtures have depressed melting points. It has a slightly bitter taste, and is not safe to drink.

Isopropyl alcohol becomes increasingly viscous with decreasing temperature and freezes at −89 °C (−128 °F).

Isopropyl alcohol has a maximal absorbance at 205 nm in an ultraviolet-visible spectrum.

Reactions

Isopropyl alcohol can be oxidized to acetone, which is the corresponding ketone. This can be achieved using oxidizing agents such as chromic acid, or by dehydrogenation of isopropyl alcohol over a heated copper catalyst:(CH₃)₂CHOH → (CH₃)₂CO + H₂

Isopropyl alcohol is often used as both solvent and hydride source in the Meerwein-Ponndorf-Verley reduction and other transfer hydrogenation reactions. Isopropyl alcohol may be converted to 2-bromopropane using phosphorus tribromide, or dehydrated to propene by heating with sulfuric acid.

Like most alcohols, isopropyl alcohol reacts with active metals such as potassium to form alkoxides that are called isopropoxides. With titanium tetrachloride, isopropyl alcohol reacts to give titanium isopropoxide:TiCl₄ + 4 (CH₃)₂CHOH → Ti(OCH(CH₃)₂)₄ + 4 HCl

This and similar reactions are often conducted in the presence of base.

The reaction with aluminium is initiated by a trace of mercury to give aluminium isopropoxide.

History

In 1920, Standard Oil first produced isopropyl alcohol by hydrating propene. Isopropyl alcohol was oxidized to acetone for the preparation of cordite, a smokeless, low explosive propellant.