Courtesy: Material safety data sheet [MSDS] certification services
This section describes:
The harmful effects of exposure
How the product is likely to enter the body and what effects it has on the
organs in the body
The short-term (acute) and long-term (chronic) health effects from exposure
to the product
The exposure limits, which indicates the maximum concentration in air of a
hazardous substance (gas, vapour, dust, mist, fume) to which nearly all
workers (without personal protective equipment) can be repeatedly exposed
without adverse health effects. Exposure limits are expressed in three ways:
o TWA (time weighted average) indicating the maximum average
concentration to which workers can safety be exposed for a normal 8-
hour workday or 48-hour workweek
o STEL (short-term exposure limit) indicating the maximum concentration to
which workers can safely be exposed for a period of up to 15 minutes.
The STEL is higher than the TWA. It may not be sustained more than four
times a day
o C (ceiling) describes the concentration that may not be safely exceeded
at any time, even for an instant. The C is higher that the STEL
If these limits are to be exceeded, the worker must use recommended
personal protective equipment. Exposure limits are expressed as ppm for
gases and vapours and as mg/m3
for dusts, fumes and mists
Note these limits may be expressed as OEL, PEL and TLV
Information used to assess the health problems of any employee who uses
the chemical and determine if that worker’s problems are related to the
chemical
This section provides:
Instruction for the safe use, handling and storage of the product
The personal protective equipment or safety devices required
The steps for cleaning up spills
Information on the waste disposal requirements
First Aid Measures:
This section describes:
Specific first aid measures related to acute effects of exposure to the product
First aid steps in the correct sequence
Information to assist in planning for emergencies
The MSDS may contain additional sections providing further information related to the
specific product.
Location of the MSDSs
Hard copy readily available
Computer terminals
Employees and others must know where the MSDS is and how to use them
MSDS revisions are required every 3 years or sooner if new product information is
available.
Trade Secret Exemptions
Information may be withheld to protect industries’ right to protect confidential business
information. This information is referred to as trade secrets.
The producer of the product can withhold:
The name and concentration of any ingredient
Name of relevant toxicological studies
Once a claim if filed to withhold information the product label must state:
Date the exemption filed
Claim registration number
The MSDS must state:
That an exemption has been granted
Date it is granted
Registry number
Product hazards
Medical Access
Doctors and nurses can access withheld information however this information remains
confidentia